SIST EN 17411:2021
(Main)Fertilizers - Determination of perchlorate in mineral fertilizers by liquid chromatography and tandem mass spectrometry detection (LC-MS/MS)
Fertilizers - Determination of perchlorate in mineral fertilizers by liquid chromatography and tandem mass spectrometry detection (LC-MS/MS)
This document specifies a method for the determination of traces of perchlorate with liquid chromatography and tandem mass spectrometry detection (LC‐MS/MS). The method is applicable to mineral fertilizers.
Düngemittel - Bestimmung von Perchlorat in mineralischen Düngemitteln - Bestimmung mittels Flüssig-Chromatographie und Tandem-Massenspektrometrischer Detektion (LC-MS/MS)
Dieses Dokument legt ein Verfahren zur Bestimmung von Perchloratspuren mittels Flüssigchromatographie und Tandem-Massenspektrometrie-Detektion (LC MS/MS) fest. Das Verfahren ist für mineralische Düngemittel anwendbar.
Engrais - Dosage du perchlorate dans les engrais minéraux par chromatographie liquide couplée à la spectrométrie de masse (LCMS/MS)
Le présent document spécifie une méthode de détermination des traces de perchlorate par chromatographie liquide couplée à la spectrométrie de masse (LC-MS/MS). La méthode est applicable aux engrais minéraux.
Gnojila - Določevanje perklorata v mineralnih gnojilih s tekočinsko kromatografijo in tandemsko masno spektrometrijo (LC-MS/MS)
General Information
Standards Content (Sample)
SLOVENSKI STANDARD
SIST EN 17411:2021
01-januar-2021
Gnojila - Določevanje perklorata v mineralnih gnojilih s tekočinsko kromatografijo
in tandemsko masno spektrometrijo (LC-MS/MS)
Fertilizers - Determination of perchlorate in mineral fertilizers by liquid chromatography
and tandem mass spectrometry detection (LC-MS/MS)
Düngemittel - Bestimmung von Perchlorat in mineralischen Düngemitteln - Bestimmung
mittels Flüssig-Chromatographie und Tandem-Massenspektrometrischer Detektion (LC-
MS/MS)
Engrais - Dosage du perchlorate dans les engrais minéraux par chromatographie liquide
couplée à la spectrométrie de masse (LCMS/MS)
Ta slovenski standard je istoveten z: EN 17411:2020
ICS:
65.080 Gnojila Fertilizers
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
SIST EN 17411:2021 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
---------------------- Page: 1 ----------------------
SIST EN 17411:2021
---------------------- Page: 2 ----------------------
SIST EN 17411:2021
EN 17411
EUROPEAN STANDARD
NORME EUROPÉENNE
November 2020
EUROPÄISCHE NORM
ICS 65.080
English Version
Fertilizers - Determination of perchlorate in mineral
fertilizers by liquid chromatography and tandem mass
spectrometry detection (LC-MS/MS)
Engrais - Dosage du perchlorate dans les engrais Düngemittel - Bestimmung von Perchlorat in
minéraux par chromatographie liquide couplée à la mineralischen Düngemitteln - Bestimmung mittels
spectrométrie de masse (LC-MS/MS) Flüssig-Chromatographie und Tandem-
Massenspektrometrischer Detektion (LC-MS/MS)
This European Standard was approved by CEN on 4 October 2020.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2020 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17411:2020 E
worldwide for CEN national Members.
---------------------- Page: 3 ----------------------
SIST EN 17411:2021
EN 17411:2020 (E)
Contents Page
European foreword . 3
1 Scope . 4
2 Normative references . 4
3 Terms and definitions . 4
4 Principle . 4
5 Reagents . 4
6 Apparatus and equipment . 5
7 Procedure. 5
7.1 Sampling and sample preparation . 5
7.2 Matrix calibration curve . 5
7.3 Determination of perchlorate in test solutions . 6
8 Calculation . 7
9 Precision . 7
9.1 Inter-laboratory test . 7
9.2 Repeatability . 7
9.3 Reproducibility . 7
10 Additional remarks . 8
11 Test report . 8
Annex A (informative) Results of the inter-laboratory test . 9
Bibliography . 10
2
---------------------- Page: 4 ----------------------
SIST EN 17411:2021
EN 17411:2020 (E)
European foreword
This document (EN 17411:2020) has been prepared by Technical Committee CEN/TC 260 “Fertilizers
and liming materials”, the secretariat of which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by May 2021, and conflicting national standards shall be
withdrawn at the latest by May 2021.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
According to the CEN-CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the
United Kingdom.
3
---------------------- Page: 5 ----------------------
SIST EN 17411:2021
EN 17411:2020 (E)
1 Scope
This document specifies a method for the determination of traces of perchlorate by liquid
chromatography and tandem mass spectrometry detection (LC-MS/MS). The method is applicable to
mineral fertilizers.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 1482-2, Fertilizers and liming materials — Sampling and sample preparation — Part 2: Sample
preparation
EN 12944-1, Fertilizers and liming materials and soil improvers — Vocabulary — Part 1: General terms
EN 12944-2, Fertilizers and liming materials and soil improvers — Vocabulary — Part 2: Terms relating
to fertilizers
EN ISO 3696, Water for analytical laboratory use — Specification and test methods (ISO 3696)
3 Terms and definitions
For the purposes of this document, the terms and definitions given in EN 12944-1 and EN 12944-2
apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— IEC Electropedia: available at http://www.electropedia.org/
— ISO Online browsing platform: available at https://www.iso.org/obp
4 Principle
The perchlorate content of the fertilizer sample is determined by li
...
SLOVENSKI STANDARD
oSIST prEN 17411:2019
01-september-2019
Gnojila - Določevanje perklorata v mineralnih gnojilih s tekočinsko kromatografijo
in z detekcijo na osnovi tandemske masne spektrometrije (LC-MS/MS)
Fertilizers - Determination of perchlorate in mineral fertilizers by liquid chromatography
and tandem mass spectrometry detection (LC-MS/MS)
Düngemittel - Bestimmung von Perchlorat in mineralischen Düngemitteln - Bestimmung
mittels Flüssig-Chromatographie und Tandem-Massenspektrometrischer Detektion (LC-
MS/MS)
Engrais — Dosage du perchlorate dans les engrais minéraux par chromatographie
liquide couplée à la spectrométrie de masse (LCMS/MS)
Ta slovenski standard je istoveten z: prEN 17411
ICS:
65.080 Gnojila Fertilizers
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
oSIST prEN 17411:2019 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
---------------------- Page: 1 ----------------------
oSIST prEN 17411:2019
---------------------- Page: 2 ----------------------
oSIST prEN 17411:2019
DRAFT
EUROPEAN STANDARD
prEN 17411
NORME EUROPÉENNE
EUROPÄISCHE NORM
July 2019
ICS 65.080
English Version
Fertilizers - Determination of perchlorate in mineral
fertilizers by liquid chromatography and tandem mass
spectrometry detection (LC-MS/MS)
Engrais - Dosage du perchlorate dans les engrais Düngemittel - Bestimmung von Perchlorat in
minéraux par chromatographie liquide couplée à la mineralischen Düngemitteln - Bestimmung mittels
spectrométrie de masse (LCMS/MS) Flüssig-Chromatographie und Tandem-
Massenspektrometrischer Detektion (LC-MS/MS)
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 260.
If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.
This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.
Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2019 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 17411:2019 E
worldwide for CEN national Members.
---------------------- Page: 3 ----------------------
oSIST prEN 17411:2019
prEN 17411:2019 (E)
Contents Page
European foreword . 3
1 Scope . 4
2 Normative references . 4
3 Terms and definitions . 4
4 Principle . 4
5 Reagents . 4
6 Apparatus and equipment . 5
7 Procedure. 5
7.1 Sampling and sample preparation . 5
7.2 Matrix calibration curve . 5
7.3 Determination of perchlorate in test solutions . 6
8 Calculation . 7
9 Precision . 7
9.1 Inter-laboratory test . 7
9.2 Repeatability . 7
9.3 Reproducibility . 7
10 Additional remarks . 8
11 Test report . 8
Annex A (informative) Results of the inter-laboratory test . 9
Bibliography . 10
2
---------------------- Page: 4 ----------------------
oSIST prEN 17411:2019
prEN 17411:2019 (E)
European foreword
This document (prEN 17411:2019) has been prepared by Technical Committee CEN/TC 260 “Fertilizers
and liming materials”, the secretariat of which is held by DIN.
This document is currently submitted to the CEN Enquiry.
3
---------------------- Page: 5 ----------------------
oSIST prEN 17411:2019
prEN 17411:2019 (E)
1 Scope
This document specifies a method for the determination of traces of perchlorate by liquid
chromatography and tandem mass spectrometry detection (LC-MS/MS). The method is applicable to
mineral fertilizers.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 12944-1, Fertilizers and liming materials and soil improvers – Vocabulary – Part 1: General terms
EN 12944-2, Fertilizers and liming materials and soil improvers – Vocabulary – Part 2: Terms relating to
fertilizers
EN ISO 3696, Water for analytical laboratory use – Specification and test methods (ISO 3696)
EN ISO 14820-2, Fertilizers and liming materials – Sampling and sample preparation – Part 2: Sample
preparation
3 Terms and definitions
For the purposes of this document, the terms and definitions given in EN 12944-1 and EN 12944-2
apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— IEC Electropedia: available at http://www.electropedia.org/
— ISO Online browsing platform: available at http://www.iso.org/obp
4 Principle
The perchlorate content of the fertilizer sample is determined by liquid chromatography with tandem
mass spectrometry detection after water extraction. The sample is dissolved, filtered and directly
analysed by LC-MS/MS. Quantification is performed using matrix calibrati
...
Questions, Comments and Discussion
Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.